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Aldrich
4-Methylmorpholine N-oxide
224286 -
97%
DOWNLOAD MSDS (PDF)Synonym: NMO
CAS Number: 7529-22-8
Empirical Formula (Hill Notation): C5H11NO2
Molecular Weight: 117.15
Beilstein Registry Number: 507437
EC Number: 231-391-8
MDL number: MFCD00005947
PubChem Substance ID: 24853425
Properties
| Related Categories | Others, Oxidation, Synthetic Reagents |
| assay | 97% |
| mp | 180-184 °C(lit.) |
Description
Application
Non-metallic catalyst for the cyanosilylation of ketones.1 Co-oxidant for Sharpless asymmetric dihydroxylation in ionic liquids.2
Packaging
25, 100 g in poly btl
5 g in glass btl
Price and Availability
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Safety Information
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36/37 |
| WGK Germany | 1 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Encapsulated Os Catalysts
Sigma-Aldrich, in collaboration with Reaxa Ltd., is pleased to offer first-to-market catalysts for use in practical synthetic transformations. Reaxa has immobilized osmium tetroxide, a toxic and vola...
Aldrich ChemFiles 2006, 6.5, 6.
Keywords: Dihydroxylations, Immobilization
Os EnCat™ 40
Sigma-Aldrich, in collaboration with Reaxa Ltd., is pleased to offer first-to-market catalysts for use in practical synthetic transformations. Reaxa has immobilized osmium tetroxide, a toxic and vola...
Aldrich ChemFiles 2006, 6.6, 5.
Keywords: Dihydroxylations, Immobilization
Related Content
Os EnCat 40 in Chmical Sythesis
Sigma-Aldrich is pleased to offer innovative catalysts for use in practical synthetic transformations in collaboration with Reaxa. Reaxa has immobilized osmium tetroxide, a toxic and volatile reagent...
References
1. Synlett 6, 1077-1079, (2004)
2. J. Org. Chem. 69, 4381-4389, (2004) Abstract
Merck 14,10470
Fieser 7,244 / Fieser 13,222
Aldrich MSDS 1, 1273:A / Corp MSDS 1 (2), 2383:D / FT-IR 2 (3), 3982:D / IR-Spectra (3), 1420:B / NMR-Reference 2 (2), 780:C / RegBook 1 (2), 2673:F / Structure Index 1, 420:B:4
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